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Facile fabrication of dolomite-doped biochar/bentonite for effective removal of phosphate from complex

《环境科学与工程前沿（英文）》 2023年 第17卷 第6期 doi: 10.1007/s11783-023-1671-7

摘要：

● Dolomite-doped biochar/bentonite was synthesized for phosphate removal.

关键词： Biochar-bentonite composite     Dolomite doping     Phosphate adsorption     Polymeric matrix membrane     Adsorption-filtration dual functions     Low-concentration phosphate    

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Highly efficient and selective removal of phosphate from wastewater of sea cucumber aquaculture for microalgae

《环境科学与工程前沿（英文）》 2023年 第17卷 第10期 doi: 10.1007/s11783-023-1720-2

摘要：

● A new adsorption-membrane separation strategy is used for phosphate removal.

关键词： Adsorption-membrane     Low-concentration phosphate     Zr-modified-bentonite     Recycle     Microalgal culture    

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Investigation of solution chemistry to enable efficient lithium recovery from low-concentration lithium-containing

Chunlong Zhao, Mingming He, Hongbin Cao, Xiaohong Zheng, Wenfang Gao, Yong Sun, He Zhao, Dalong Liu, Yanling Zhang, Zhi Sun

《化学科学与工程前沿（英文）》 2020年 第14卷 第4期   页码 639-650 doi: 10.1007/s11705-019-1806-3

摘要： In the production of lithium-ion batteries (LIBs) and recycling of spent LIBs, a large amount of low-concentration lithium-containing wastewater (LCW) is generated. The recovery of Li from this medium has attracted significant global attention from both the environmental and economic perspectives. To achieve effective Li recycling, the features of impurity removal and the interactions among different ions must be understood. However, it is generally difficult to ensure highly efficient removal of impurity ions while retaining Li in the solution for further recovery. In this study, the removal of typical impurity ions from LCW and the interactions between these species were systematically investigated from the thermodynamic and kinetics aspects. It was found that the main impurities (e.g., Fe , Al , Ca , and Mg ) could be efficiently removed with high Li recovery by controlling the ionic strength of the solution. The mechanisms of Fe , Al , Ca , and Mg removal were investigated to identify the controlling steps and reaction kinetics. It was found that the precipitates are formed by a zero-order reaction, and the activation energies tend to be low with a sequence of fast chemical reactions that reach equilibrium very quickly. Moreover, this study focused on Li loss during removal of the impurities, and the corresponding removal rates of Fe , Al , Ca , and Mg were found to be 99.8%, 99.5%, 99%, and 99.7%, respectively. Consequently, high-purity Li PO was obtained via one-step precipitation. Thus, this research demonstrates a potential route for the effective recovery of Li from low-concentration LCW and for the appropriate treatment of acidic LCW.

关键词： lithium-containing wastewater     lithium phosphate     precipitation     impurity ion    

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Scrap Iron Filings assisted nitrate and phosphate removal in low C/N waters using mixed microbial culture

《环境科学与工程前沿（英文）》 2021年 第15卷 第4期 doi: 10.1007/s11783-020-1358-2

摘要：

• Microbes enhance denitrification under varying DO concentrations and SIF dosages.

关键词： Scrap iron filing     Nitrate removal     Phosphate removal     Mixed culture denitrification     Zero valent iron    

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Characterization of chlorine dioxide as disinfectant for the removal of low concentration microcystins

Mingsong WU, Junli HUANG, Yuling ZHANG, Shijie YOU, Shaofeng LI, Zhilin RAN, Yu TIAN

《环境科学与工程前沿（英文）》 2012年 第6卷 第1期   页码 75-81 doi: 10.1007/s11783-011-0331-5

摘要： Microcystins, which represents one kind of cancerogenic organic compounds, is abundant in eutrophication water. The effects of reaction factors on chlorine dioxide (ClO ) for removal of low-concentration Microcystin-LR, Microcystin-RR, and Microcystin-YR in water as well as the reaction mechanisms was investigated by using enzyme-linked immunosorbent assay (ELISA) kit and gas chromatography–mass spectrometry (GC-MS). The results showed that MC-LR, MC-RR, and MC-YR could be efficiently decomposed by ClO . The degradation efficiency was shown positively correlated to the concentration of ClO and reaction time; while the effect of reaction temperature and pH is slight. The kinetic constants and activation energies of the reaction of MC-LR, MC-RR, and MC-YR with ClO are determined as 459.89, 583.15, 488.43 L·(mol·min) and 64.78, 53.01, 59.15 kJ·mol , respectively. As indicated by high performance liquid chromatography mass spectrometer (HPLC-MS) analysis, degradation should be accomplished via destruction of Adda group by oxidation, with the formation of dihydroxy substituendums as end products. This study has provided a fundamental demonstration of ClO serving as oxidizing disinfectant to eliminate microcystins from raw water source.

关键词： disinfection     chlorine dioxide     microcystins     reaction mechanism    

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消光法测定磷酸铵盐微粒灭火剂灭火浓度研究

殷志平,刘爱华,潘仁明

《中国工程科学》 2008年 第10卷 第7期   页码 90-95

摘要：

采用过滤称重法配合激光消光法对两种粒度的磷酸铵盐微粒灭火剂在杯式燃烧器中的灭火浓度进行了研究，得出了激光测定磷酸铵盐微粒灭火剂的质量浓度标定曲线和微粒灭火剂的灭火浓度。结果表明，在该实验条件下，平均粒度分别为6.0 μm和13.7 μm的磷酸铵盐微粒灭火剂其激光吸收发散系数K值分别为0.353 0 m2/g和0.257 3 m2/g，平均灭火质量浓度分别为32.9 g/m3和41.6 g/m3，前者的灭火效能比后者高出25 % ～ 30 %，且前者采用激光消光法测定时相对误差较小。

关键词： 激光消光法     过滤称重法     微粒灭火剂     灭火浓度    

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Phosphorus release potential and pollution characteristics of sediment in downstream Nansi Lake, China

Zhijian LI, Qinyan YUE, Baoyu GAO, Yanwen WANG, Qing LIU

《环境科学与工程前沿（英文）》 2012年 第6卷 第2期   页码 162-170 doi: 10.1007/s11783-011-0313-7

摘要： The research aimed to evaluate present and potential phosphorous pollution due to high sedimentary phosphorus load and release from sediment, when external phosphorus was reduced in downstream Nansi Lake. Pollution load of the sediment and overlying water was investigated. Kinetics and isotherms of adsorption/release of sedimentary phosphorus were studied to determine equilibrium phosphate concentration (EPC ) and release potential. Kinetics of phosphorus adsorption on sediment and release from sediment were well described by both the pseudo-first-order rate equation and the pseudo-second-order rate equation, but more appropriate to the pseudo-second-order rate equation with the adsorption/release capacity more close to the measured values, suggesting that the processes were chemically rate controlled and dependent on adsorption capacity. Soluble reactive phosphorus (SRP) sorption isotherms on sediment were best fitted by the modified Langmuir model indicating a monolayer adsorption. By comparing EPC and SRP of water, the status (adsorption, releasing or in equilibrium) of sediment phosphorus could be determined. The sediments at site S1, S3, S4, S5, and S7 where the EPC s were greater than the SRPs, had a potential to release phosphorus into the water column. However, those sediments at S9, S10, and S12, where the EPC s were approximately equal to the SRPs, were in impermanent equilibrium with overlying water in status of phosphorus, the sediments can be likely to release phosphorus to the water column once the equilibrium was broken. Therefore, sedimentary phosphorus can be a secondary pollution source in downstream Nansi Lake.

关键词： Nansi Lake     sediment     phosphorus     release potential     equilibrium phosphate concentration    

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An experimental study on ignition of single coal particles at low oxygen concentrations

Wantao YANG, Yang ZHANG, Lilin HU, Junfu LYU, Hai ZHANG

《能源前沿（英文）》 2021年 第15卷 第1期   页码 38-45 doi: 10.1007/s11708-020-0692-1

摘要： An experimental study on the ignition of single coal particles at low oxygen concentrations ( <21%) was conducted using a tube furnace. The surface temperature ( ) and the center temperature ( ) of the coal particles were obtained from the images taken by an infrared camera and thermocouples respectively. The ignition processes were recorded by a high-speed camera at different values and furnace temperatures . Compared with literature experimental data obtained at a high value, the ignition delay time decreases more rapidly as increases at the low region. The responses of and to the variation of are different: decreases while remains nearly constant with increasing at a low value. In addition, is less sensitive to while the ignition temperature is more sensitive to at a low value than in air. Observations of the position of flame front evolution illustrate that the ignition of a coal particle may change from a homogeneous mode to a heterogeneous or combined ignition mode as decreases. At a low value, buoyancy plays a more significant role in sweeping away the released volatiles during the ignition process.

关键词： coal particles     low oxygen concentration     ignition     ignition temperature     ignition modes    

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Enhanced adsorption of phosphate by loading nanosized ferric oxyhydroxide on anion resin

Jing REN,Nan LI,Lin ZHAO,Nanqi REN

《环境科学与工程前沿（英文）》 2014年 第8卷 第4期   页码 531-538 doi: 10.1007/s11783-014-0629-1

摘要： Ferric oxyhydroxide loaded anion exchanger (FOAE) hybrid adsorbent was prepared by loading nanosized ferric oxyhydroxide (FO) on anion exchanger resin for the removal of phosphate from wastewater. TEM and XRD analysis confirmed the existence of FO on FOAE. After FO loading, the adsorption capacity of the hybrid adsorbent increased from 38.70 to 51.52 mg·g . Adsorption processes for both FOAE and anion resin were better fit to the pseudo first order model. Batch adsorption experiments revealed that higher temperature (313K), higher initial phosphate concentration (50 mg·L ) and lower solution pH (pH value of 2) would be more propitious to phosphate adsorption. Competition effect of coexisting anions on phosphate removal can be concluded as sulfate>nitrate>chloride. Freundlich isotherm model can describe the adsorption of phosphate on FOAE more accurately, which indicated the heterogeneous adsorption occurred on the inner-surface of FOAE.

关键词： phosphate removal     adsorption     nanosized ferric oxyhydroxide     anion exchanger    

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A potentiometric cobalt-based phosphate sensor based on screen-printing technology

Lei ZHU,Xiaohong ZHOU,Hanchang SHI

《环境科学与工程前沿（英文）》 2014年 第8卷 第6期   页码 945-951 doi: 10.1007/s11783-013-0615-z

摘要： A potentiometric cobalt-based screen-printing sensor was fabricated by electroplating cobalt on the surface of a screen-printing electrode as the sensitive layer for the determination of dihydrogenphosphate ( ) in wastewater samples. The electrochemical performance of this sensor was fully examined to determine its detection calibration, detection limit, response time, selectivity, and interference with pH, various ions, and dissolved oxygen (DO). The cobalt-based phosphate sensor showed a phosphate-selective potential response in the range of 10 mol·L to 10 mol·L , yielding a detection limit of 3.16 × 10 mol?L and a slope of -37.51 mV?decade in an acidic solution (pH 4.0) of . DO and pH were found to interfere with sensor responses to phosphate. Ultimately, the performance of the sensor was validated for detecting wastewater samples from the Xiaojiahe Wastewater Treatment Plant against the standard spectrophotometric methods for analysis. The discrepancy between the two methods was generally ±5% (relative standard deviation). Aside from its high selectivity, sensitivity, and stability, which are comparable with conventional bulk Co-wire sensors, the proposed phosphate sensor presents many other advantages, such as low price, compactness, ease of use, and the possibility of integration with other analytical devices, such as flow injectors.

关键词： phosphate     cobalt     screen-printing technology     electroplate     wastewater    

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料浆法磷铵生产工艺发展与五大磷肥工程改造

钟本和

《中国工程科学》 2004年 第6卷 第6期   页码 22-25

摘要：

针对引进磷酸浓缩工艺生产磷铵的技术不适应我国矿产资源具体情况的难题，开发了料浆法磷铵生产工艺技术，已在21个省区布点推广建设了87套装置，形成生产能力279×104 t/a的规模，占全国磷铵生产能力的60%。最近在贵州瓮福实施料浆法磷铵与引进的传统磷酸浓缩工艺联产的成功，为五大磷肥工程的改造提供了一条新的途径。

关键词： 磷肥     磷铵     料浆法磷铵    

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Thermogravimetric coupled with Fourier transform infrared analysis study on thermal treatment of monopotassium phosphate

Yuheng FENG, Xuguang JIANG, Yong CHI, Xiaodong LI, Hongmei ZHU

《环境科学与工程前沿（英文）》 2011年 第5卷 第2期   页码 186-192 doi: 10.1007/s11783-011-0322-6

摘要： In China, safe disposal of hazardous waste is more and more a necessity, urged by rapid economic development. The pyrolysis and combustion characteristics of a residue from producing monopotassium phosphate (monopotassium phosphate residue), considered as a hazardous waste, were studied using a thermogravimetric, coupled with Fourier transform infrared analyzer (TG-FTIR). Both pyrolysis and combustion runs can be subdivided into three stages: drying, thermal decomposition, and final devolatilization. The average weight loss rate during fast thermal decomposition stage in pyrolysis is higher than combustion. Acetic acid, methane, pentane, (acetyl) cyclopropane, 2,4,6-trichlorophenol, CO, and CO were distinguished in the pyrolysis process, while CO was the dominant combustion product.

关键词： hazardous waste     combustion     pyrolysis     thermogravimetric coupled with Fourier transform infrared analysis (TG-FTIR)     monopotassium phosphate residue    

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Localized high-concentration electrolytes for lithium metal batteries: progress and prospect

《化学科学与工程前沿（英文）》 2023年 第17卷 第10期   页码 1354-1371 doi: 10.1007/s11705-022-2286-4

摘要： With the increasing development of digital devices and electric vehicles, high energy-density rechargeable batteries are strongly required. As one of the most promising anode materials with an ultrahigh specific capacity and extremely low electrode potential, lithium metal is greatly considered an ideal candidate for next-generation battery systems. Nevertheless, limited Coulombic efficiency and potential safety risks severely hinder the practical applications of lithium metal batteries due to the inevitable growth of lithium dendrites and poor interface stability. Tremendous efforts have been explored to address these challenges, mainly focusing on the design of novel electrolytes. Here, we provide an overview of the recent developments of localized high-concentration electrolytes in lithium metal batteries. Firstly, the solvation structures and physicochemical properties of localized high-concentration electrolytes are analyzed. Then, the developments of localized high-concentration electrolytes to suppress the formation of dendritic lithium, broaden the voltage window of electrolytes, enhance safety, and render low-temperature operation for robust lithium metal batteries are discussed. Lastly, the remaining challenges and further possible research directions for localized high-concentration electrolytes are outlined, which can promisingly render the practical applications of lithium metal batteries.

关键词： high-concentration electrolyte     localized high-concentration electrolyte     lithium metal battery     solid electrolyte interphase     dendrite    

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PM concentration declining saves health expenditure in China

《环境科学与工程前沿（英文）》 2023年 第17卷 第7期 doi: 10.1007/s11783-023-1690-4

摘要：

● Monthly hospitalization expenses are sensitive to increases in PM2.5 exposure.

关键词： Air pollution     Health expenditure     PM2.5 concentration     Economic impact     Heterogeneous effect    

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Highly selective and green recovery of lithium ions from lithium iron phosphate powders with ozone

《化学科学与工程前沿（英文）》 2023年 第17卷 第6期   页码 749-758 doi: 10.1007/s11705-022-2261-0

摘要： Since lithium iron phosphate cathode material does not contain high-value metals other than lithium, it is therefore necessary to strike a balance between recovery efficiency and economic benefits in the recycling of waste lithium iron phosphate cathode materials. Here, we describe a selective recovery process that can achieve economically efficient recovery and an acceptable lithium leaching yield. Adjusting the acid concentration and amount of oxidant enables selective recovery of lithium ions. Iron is retained in the leaching residue as iron phosphate, which is easy to recycle. The effects of factors such as acid concentration, acid dosage, amount of oxidant, and reaction temperature on the leaching of lithium and iron are comprehensively explored, and the mechanism of selective leaching is clarified. This process greatly reduces the cost of processing equipment and chemicals. This increases the potential industrial use of this process and enables the green and efficient recycling of waste lithium iron phosphate cathode materials in the future.

关键词： lithium iron phosphate powder     stoichiometric number     selective leaching     lithium recovery    

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标题 作者 时间 类型 操作

Facile fabrication of dolomite-doped biochar/bentonite for effective removal of phosphate from complex

期刊论文

Highly efficient and selective removal of phosphate from wastewater of sea cucumber aquaculture for microalgae

期刊论文

Investigation of solution chemistry to enable efficient lithium recovery from low-concentration lithium-containing

Chunlong Zhao, Mingming He, Hongbin Cao, Xiaohong Zheng, Wenfang Gao, Yong Sun, He Zhao, Dalong Liu, Yanling Zhang, Zhi Sun

期刊论文

Scrap Iron Filings assisted nitrate and phosphate removal in low C/N waters using mixed microbial culture

期刊论文

Characterization of chlorine dioxide as disinfectant for the removal of low concentration microcystins

Mingsong WU, Junli HUANG, Yuling ZHANG, Shijie YOU, Shaofeng LI, Zhilin RAN, Yu TIAN

期刊论文

消光法测定磷酸铵盐微粒灭火剂灭火浓度研究

殷志平,刘爱华,潘仁明

期刊论文

Phosphorus release potential and pollution characteristics of sediment in downstream Nansi Lake, China

Zhijian LI, Qinyan YUE, Baoyu GAO, Yanwen WANG, Qing LIU

期刊论文

An experimental study on ignition of single coal particles at low oxygen concentrations

Wantao YANG, Yang ZHANG, Lilin HU, Junfu LYU, Hai ZHANG

期刊论文

Enhanced adsorption of phosphate by loading nanosized ferric oxyhydroxide on anion resin

Jing REN,Nan LI,Lin ZHAO,Nanqi REN

期刊论文

A potentiometric cobalt-based phosphate sensor based on screen-printing technology

Lei ZHU,Xiaohong ZHOU,Hanchang SHI

期刊论文

料浆法磷铵生产工艺发展与五大磷肥工程改造

钟本和

期刊论文

Thermogravimetric coupled with Fourier transform infrared analysis study on thermal treatment of monopotassium phosphate

Yuheng FENG, Xuguang JIANG, Yong CHI, Xiaodong LI, Hongmei ZHU

期刊论文

Localized high-concentration electrolytes for lithium metal batteries: progress and prospect

期刊论文

PM concentration declining saves health expenditure in China

期刊论文

Highly selective and green recovery of lithium ions from lithium iron phosphate powders with ozone

期刊论文